You can add a new key-value to an existing dictionary using one of the following approaches:
1. Using update() function:
>>> aa={'a':1,'b':2}
>>> aa.update({'c':3})
>>> aa
{'a': 1, 'b': 2, 'c': 3}
2. Using new key as an index:
>>> aa['d']=4
>>> aa
{'a': 1, 'b': 2, 'c': 3, 'd': 4}